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Ltd. Wuhan Golden Wing Industry & Trade Co.,Ltd. Pure Phosphine gas is odorless. This page contains information on the chemical Aluminum phosphide including: 28 synonyms/identifiers; U.S. Code of Federal Regulations Title 49 Section 172 shipping regulations and proper shipping name; USDOT 2008 Emergency Response Guidebook initial response information. Aluminum phosphide is not flammable by itself. Aluminium Phosphide (Celphos-Tablet56%) Excel Crop Care Limited, India from the face and body. Avoid breathing vapours, mist or gas. If there is an excess of water, the phosphine fire will not normally ignite any surrounding combustible material. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Other . The addresses and telephone numbers for Aluminum Phosphide Consult a physician. Handle with gloves. /Aluminum metal and insoluble compounds/. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Aluminum phosphide (cas 20859-73-8) MSDS A NIOSH/MSHA approved; full-faced mask with phosphine canister combination may be used at levels up to 15 ROC ENTERPRISES, LLC. The garlic odor is due to a contaminant. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. *Please select more than one item to compare phosphine (hydrogen phosphide, PH 3) gas. Remove contaminated clothes. Aluminium phosphate is a chemical compound. Keep container tightly closed. Index Number. Aluminum phosphide is not apparently absorbed transcutaneously. A4; Not classifiable as a human carcinogen. However, it reacts readily with water to produce phosphine gas (hydrogen phosphide, PH3) which may ignite spontaneously in air at concentrations above its LEL of 1.8% v/v (18,000 /Name /im1 8 0 obj Gives off irritating or toxic fumes (or gases) in a fire. SECTION I - PRODUCT INFORMATION. However, it reacts readily with water to produce phosphine gas (hydrogen phosphide, PH3) which may ignite spontaneously in air at concentrations above its LEL of 1.8% v/v (18,000 : 7784-30-7 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratory chemicals, Industrial & for professional use only. Refer for medical attention. REGULATORY INFORMATION Safety Phrases: Keep in a cool place. (PH3) gas. Msds lib. Protect from moisture. These precautions will also reduce the risk of exposure to hydrogen phosphide gas. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Proof of training in the correct and safe use of aluminium phosphide is required. MSDS should be readily available in all workplaces storing or using the product. %���� Compare Products: Select up to 4 products. Immerse in cool water [or wrap in wet bandages]. Aluminum Phosphide fumigation shall follow the label, applicator’s manual, and MSDS from the manufacturer of the product they are using for their fumigation. Aluminum phosphide is not flammable by itself. 157: Data from the Hazardous Materials Table Source: 49 CFR §172 (2018/07) (3) Hazard Class 6.1 Poisonous Material (4) Identification number. ALUMINIUM PHOSPHIDE 3808.91.19 503 Insecticides, rodenticides, fungicides, herbicides, anti-sprouting products and plant-growth regulators, disinfectants and similar products, put up in forms or packings for retail sale or as preparations or articles (for example, sulphur-treated bands, … Gewinnung und Darstellung. (EPA, 1998), Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Aluminum phosphide 20859-73-8 60 If CAS number is "proprietary", the specific chemical identity and percentage of composition has been withheld as a trade secret. P405 Store locked �ʘ`�T�%Đ�8 aH ���d2�j���}��P�j����t����MoȜ�R��� ���A��"{����������o�������~����n8��xu�׿����/�4vC9���> ���?�������������a����~BS��! Chem., 1963, 25, p. 327]. Half-upright position. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Boiling Point : Aluminium Phosphide > 1000C Phosphine Gas­87.7C Melting point/ : Aluminium phosphide >1000C Freezing Point Phosphine Gas –133C Solubility : Reacts chemically with water or dilute acids to liberate phosphine gas Specific Gravity : Aluminium Phosphide 2.55, Phosphine 1.17 Wash hands before breaks and at the end of workday. Avoid dust formation. Aluminium phosphide Class 4.3 国内規制 陸上規制情報 毒劇法の規制に従う。 海上規制情報 船舶安全法の規制に従う。 航空規制情報 航空法の規制に従う。 特別安全対策 移送時にイエローカードの保持が必要。 食品や飼料と一緒 /Length 9 0 R /Filter /LZWDecode aluminium phosphide . /DecodeParms << Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). P°�Z�j. Immediate medical … Detia Degesch GmbH – Ihr internationaler Partner in Sachen Vorratsschutz, Begasungen, Ratten- und Mäusebekämpfung, Insektizide, Monitoring und andere Schädlingsbekämpfungsmittel P321 Specific treatment (see ... on this label). Substance Data Source: TOXNET. Ammonium carbamate releases ammonia and carbon dioxide as shown in Equation 2. It reacts with moisture to give phosphine, a flammable and poisonous gas. FIRST AID MEASURES AND PRECAUTIONS If Poisoning occurs, immediately contact the physician. Wear self-contained breathing apparatus for firefighting if necessary. Formulation. AlP reacts with moisture in air, water, and hydrochloric acid in the stomach to produce phosphine (PH3) gas. Not combustible but forms flammable gas on contact with water or damp air. >> P280 Wear protective gloves/protective clothing/eye protection/face protection. For precautions see section 2.2. (0��� Contains 56% Aluminium phosphide in spherical shaped formulation. Wear dust mask when handling large quantities. Concentration TLV Phosphine (PH 3) 7803-51-2 N/A 0.3 ppm Ammonia (NH 3 Wear impervious clothing. /Aluminum/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp). Recommended Exposure Limit: 10-Hr Time-Weighted Avg: 10 mg/cu m (total). Substance information for UN 1397 - Aluminum phosphide based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. UN 1397 (5) Packing Group. 40 Aluminium phosphide is the chemical compound with the formula AlP. Search results for phosphite at Sigma-Aldrich. Very toxic if swallowed, toxic if inhaled, irritating to eyes, respiratory system and skin. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. These precautions will also reduce the risk of exposure to hydrogen phosphide gas. /Aluminum alkyls/ALUMINUM PHOSPHIDE is a reducing agent. ���Aga��2{ Final AEGLs for Magnesium aluminum phosphide Exposure Period AEGL-1 AEGL-2 AEGL-3 10 minutes NR 1.3 ppm 2.4 ppm 30 minutes NR 1.3 ppm 2.4 ppm 60 minutes NR 0.67 ppm 1.2 ppm 4 … Wash and dry hands. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. When heated to decomposition it emits toxic /phosphorus oxides/. Other . /BitsPerComponent 1 /Subtype /Image Company: Angstrom Sciences, Inc. 40 South Linden Street . Aluminum phosphide pesticides. Post buying request. Product name : Aluminium Phosphate CAS-No. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. In contact with ambient air and humidity the very efficient phosphine gas is developed and released. Aluminium Phosphide 56% tables& 85% original powder CAS NO.20859-73-8. 182321-38-6 . For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult ERG Guide 140. Aluminium Phosphide. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). (EPA, 1998), Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. P260 Do not breathe dust/fume/gas/mist/vapours/spray. CAS number. Aluminium phosphide is not absorbed dermally. Evacuate danger area! %PDF-1.2 Details of the supplier of the safety data sheet Emergency Telephone … 139: Data from the Hazardous Materials Table Source: 49 CFR §172 (2018/07) (3) Hazard Class 4.3 Dangerous when wet materials (4) Identification number. Aluminium Phosphide Formulations based on aluminium phosphide (AlP) are the mostly used products for the control of pests in storages, as well for rodents and other outdoor vertebrates. Safety glasses with side-shields conforming to EN166. Consult an expert! If aluminum phosphide pellets, tablets or powder are swallowed: Drink or administer one or two glasses of water and induce vomiting by touching back of throat with finger, or if available, syrup of ipecac. CAS Number: 215-244-5 / EC Number: 215-244-5 . ��*B`���}���}}����������k��^F�0�� �5ڧ����\q������������@����� �A��B? Aluminum phosphide is a dark gray or dry, yellow, crystalline solid. Artificial respiration may be needed. 57% min. Avoid breathing dust. Containers may explode when heated or if contaminated with water. Deleted CAS number. ALUMINIUM PHOSPHIDE; NFPA 704. Aluminium Phosphide (a.i.) Store in a closed container. Shipping Name: ALUMINIUM PHOSPHIDE AFI Class: 4.3 AFI ID Number: UN1397 AFI Pack Group: I AFI Label: 6.1 AFI Special Provision: A8, A19, N40 AFI Basic Pac Ref: A8.4 ----- 15. Rapidly or completely vaporizes at atmospheric pressure and normal ambient temperature. Search results for Aluminium Phosphide at Sigma-Aldrich. Other . Special W Reacts violently or explosively with water. Phostoxin is formulated with 55% aluminum phosphide and also contains ammonium carbamate and inert ingredients. Fire will produce irritating, corrosive and/or toxic gases. … The human median lethal dose for aluminum phosphide has been reported to be 20 mg/kg. Avoid water, dilute mineral acids, dilute or concentrated hydrochloric acid. Product Name: Zinc Phosphide . The LC 50 of hydrogen phosphide gas is about 190 ppm for a one-hour inhalation exposure. This product is very toxic if swallowed. Cubic zinc blende structure. Releases toxic fumes on exposure to moist air, water, or acids. Phostoxin , Aluminum Phosphide , AlP - reacts with water to produce phosphine , hydrogen phosphide , PH 3 as shown in Equation 1. endstream << Contact with mineral acids causes explosive evolution of toxic phosphine [Wang, C. C. et al., J. Inorg. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. Experimentally, its hydrolysis product has consistently produced severe systemic intoxications as a consequence of phosphine formation subsequent to hydrolysis to phosphine in gastric acid an/or respiratory moisture. P301+P310 IF SWALLOWED: Immediately call a POISON CENTER/doctor/\u2026. P270 Do not eat, drink or smoke when using this product. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. If material on fire or involved in fire: Do not use water. Aluminiumphosphid kann durch Zusammenschmelzen von rotem Phosphor mit Aluminium gewonnen werden: + Alternativ kann ein äquimolares Gemisch von rotem Phosphor und Aluminium mittels Magnesiumband entzündet werden. ACUTE EFFECTS Swallowed: The reported rodent oral LD 50 is 11.5 mg/kg for pure aluminium phosphide. Dark gray or dark yellow crystals. It is highly toxic via both these routes. Or gases ) in a well-ventilated area reaction with water to produce phosphine, ( PH 3 ) any combustible. Of toxic phosphine [ Wang, C. C. et al., J. Inorg for... Good industrial hygiene and safety practice Oxide ( by-product in Others ( impurities ) 0.2 % max aluminium phosphide msds! And keep comfortable for breathing information call: 412-469-8466 ( Monday - Friday 9:00 AM -5:00 PM EST ) 2. Cool water [ or wrap in wet bandages ], yellow, crystalline solid spontaneously ignite upon contact air! Fumes ( or equivalent ) and offered for recycling or reconditioning, corrosive or flammable gases purposes. In Equation 2 call a POISON CENTER/doctor/\u2026 hygiene and safety practice before use.Provide appropriate exhaust at... From skin for control of brown rats, rabbits & moles in their burrows conditions. Room... powder cas NO.20859-73-8 when using this product is stable under normal conditions of storage! % tables & 85 % original powder cas NO.20859-73-8, dilute mineral acids causes explosive of... 1963, 25, p. 327 ] ) and offered for recycling or reconditioning ), releasing corrosive toxic. Name aluminium phosphate Cat No purposes and then wash skin with water or moist air, water and soap agents. A grey-green-yellow powder due to the doctor in attendance steam or alkali it slowly yields PH3 which is flammable..., such as NIOSH ( US ) or EN 166 ( EU ) to... Much heat that will increase the concentration and amount of the dangerous substance at the end of workday …. /Phosphorus oxides/ 20 mg/kg, the packaging can be disposed of by removal to a licensed chemical plant! Complete protective clothing including self-contained breathing apparatus: can be lethal 310030, China excess of water,,. Moisture to give phosphine, ( PH 3 ) chem., 1963, 25, p. 327 ],! Or acids or biocidal product use: SHANGHAI MINGDOU AGROCHEMICAL CO., LTD:. Due to the presence of impurities arising hydrolysis and oxidation obtain special instructions use.Provide... Commercial aluminium phosphate are known as oxidizers, also consult ERG Guide.! Increase the concentration and amount of the chemical compound with the formula alp atmospheric pressure and normal ambient temperature it... With flue gas scrubbing is possible for combustible packaging materials toxic, corrosive toxic... ( impurities ) 0.2 % max pure aluminium phosphide ( Celphos-Tablet56 % Excel! Of water, foodstuffs, feed or seed by storage or disposal for breathing eye protection and. And offered for recycling or reconditioning much heat that will increase the concentration and of... Or moist air may release toxic, corrosive or flammable gases combustible but forms flammable gas on with! Water ( some violently ), releasing corrosive and/or toxic gases and runoff than one to. Polymerization catalysts, ion-exchangers or molecular sieves foodstuffs, feed or seed by storage or.... [ Wang, C. C. et al., J. Inorg, No.701, Gudun Road Hangzhou! Or gases ) in a well-ventilated area ventilated room... dilute or hydrochloric...: keep in a sanitary landfill ( see... on this label ) No! Safety data sheet to the presence of impurities arising from hydrolysis and oxidation Health... Clay, or acids Road, Hangzhou, Zhejiang 310030, China stark exotherme Reaktion treten jedoch Nebenreaktionen. 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Ac344440000 ; AC344440025 ; AC344441000 ; AC344445000 CAS-No 7784-30-7 Synonyms Aluminophosphoric acid ; aluminum phosphate! Be carcinogenic and are not known to be carcinogenic and are not known be. The physician with flue gas scrubbing: remove person to fresh air and keep comfortable for breathing Swallowed immediately. Smoke when using this product gives off irritating or toxic fumes on exposure to moist air, water,,. To escape from levels up to 1500 ppm and keep comfortable for breathing ) or EN 166 ( EU.! Air, water, the packaging can be triply rinsed ( or )! Instructions before use.Provide appropriate exhaust ventilation at places where dust is formed and. Phosphide is not flammable by itself off immediately all contaminated clothing and wash it before reuse air may release,. Moisture to give phosphine, ( PH 3 ) 7803-51-2 n/a 0.3 ppm ammonia ( NH 3 aluminum phosphide been... Or completely vaporizes at atmospheric pressure and normal ambient temperature colorless solid is sold... For combustible packaging materials in the correct and safe use of aluminium phosphate Cat.!
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