ZINC PHOSPHIDE . 6 0 obj The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. /Aluminum/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 2 mg/cu m. /Aluminum (soluble salts and alkyls, as Al)/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m. /Aluminum (pyro powders and welding fumes, as Al)/. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). >> FIRST AID MEASURES AND PRECAUTIONS If Poisoning occurs, immediately contact the physician. For personal protection see section 8. P320 Specific treatment is urgent (see ... on this label). /Type /XObject Compare Products: Select up to 4 products. Signs and Symptoms of Exposure: Magnesium phosphide fumigant products react with moisture from the air, acids and many other liquids to release hydrogen phosphide (phosphine, PH 3) gas. 1302-45-0 . Aluminium phosphide Class 4.3 国内規制 陸上規制情報 毒劇法の規制に従う。 海上規制情報 船舶安全法の規制に従う。 航空規制情報 航空法の規制に従う。 特別安全対策 移送時にイエローカードの保持が必要。 食品や飼料と一緒 Avoid contact with skin and eyes. endstream P280 Wear protective gloves/protective clothing/eye protection/face protection. UN 1397 (5) Packing Group. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Other . stream The garlic odor is due to a contaminant. Details of the supplier of the safety data sheet Emergency Telephone … Aluminum phosphide pesticides. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2020 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, Rhodium atomic absorption standard solution, Wuhan Haizheng Industry & Trade Development Co. Ltd. Wuhan Golden Wing Industry & Trade Co.,Ltd. P°�Z�j. P302+P352 IF ON SKIN: Wash with plenty of water/... P312 Call a POISON CENTER/doctor/\u2026if you feel unwell. %���� Bioaccumulative Potential:Bioaccumulation is not expected to occur. Ammonium carbamate releases ammonia and carbon dioxide as shown in Equation 2. Evacuate personnel to safe areas. Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). Chronic toxicity: Rats fed aluminium phosphide-fumigated /DecodeParms << Substance information for UN 1397 - Aluminum phosphide based on the Hazardous Materials Table (Title 49 CFR 172.101) to assist in preparing a risk assessment for loading, transporting and storing hazardous materials. Aluminium phosphide is a highly toxic inorganic compound with the chemical formula AlP used as a wide band gap semiconductor and a fumigant. Ammonium carbamate releases ammonia and carbon dioxide which serve as a warning agent. ACUTE EFFECTS Swallowed: The reported rodent oral LD 50 is 11.5 mg/kg for pure aluminium phosphide. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P284 [In case of inadequate ventilation] wear respiratory protection. 4. Wear protective gloves when administering first aid. Product Name Aluminium phosphate Cat No. phosphine (hydrogen phosphide, PH 3) gas. SECTION I - PRODUCT INFORMATION. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution. << AlP reacts with moisture in air, water, and hydrochloric acid in the stomach to produce phosphine (PH3) gas. Blanket release with dry sand, clay, or ground limestone. [3] Commercial aluminium phosphate gel is available. Fire will produce irritating, corrosive and/or toxic gases. Aluminium phosphide ingested orally reacts with water and stomach acids to produce phosphine gas, which may account in a large part for observed toxicity. 1) AlP + 3H 2 O ---> Al(OH) 3 + PH 3 2) NH 2 COONH 4---> 2NH 3 + CO … In case of emergency: ... (PH3) present as ALUMINIUM PHOSPHIDE Each 3 g Tablet liberates 1 … For UN1796, UN1826, UN2031 at high concentrations and for UN2032, these may act as oxidizers, also consult ERG Guide 140. Shovel into suitable dry container. phosphide (phosphine, PH 3) gas produced by these chemicals has an odor described as similar to garlic, carbide or decaying fish. Aluminum phosphide is not flammable by itself. Consult an expert! /Height 310 Aluminum Phosphide fumigation shall follow the label, applicator’s manual, and MSDS from the manufacturer of the product they are using for their fumigation. Fireproof. ���Aga��2{ Aluminum phosphide (AlP) is an effective and cheap pesticide that is commonly used worldwide, but it is also a common cause of human poisoning and carries a high mortality rate. 20859-73-8 . Paraffin wax (adhesive) 3.8% max. Carefully collect remainder. Boiling Point : Aluminium Phosphide > 1000C Phosphine Gas­87.7C Melting point/ : Aluminium phosphide >1000C Freezing Point Phosphine Gas –133C Solubility : Reacts chemically with water or dilute acids to liberate phosphine gas Specific Gravity : Aluminium Phosphide 2.55, Phosphine 1.17 Inhaled aluminium phosphide dust undergoes the same reaction in the moist air sacs of the lung, although at a lower rate, resulting in similar local and systemic effects. Shipping Name: ALUMINIUM PHOSPHIDE AFI Class: 4.3 AFI ID Number: UN1397 AFI Pack Group: I AFI Label: 6.1 AFI Special Provision: A8, A19, N40 AFI Basic Pac Ref: A8.4 ----- 15. Contact with mineral acids causes explosive evolution of toxic phosphine [Wang, C. C. et al., J. Inorg. Detia Degesch GmbH – Ihr internationaler Partner in Sachen Vorratsschutz, Begasungen, Ratten- und Mäusebekämpfung, Insektizide, Monitoring und andere Schädlingsbekämpfungsmittel Concentration TLV Phosphine (PH 3) 7803-51-2 N/A 0.3 ppm Ammonia (NH 3 CAS-Number 20859-73-8: Flash Point n/a: Boiling Point n/a: Emergency Response Guide No. Deleted CAS number. In nature it occurs as the mineral berlinite. Phostoxin is formulated with 55% aluminum phosphide and also contains ammonium carbamate and inert ingredients. Aluminium phosphide is the chemical compound with the formula AlP. /Aluminum/, Recommended Exposure Limit: 10 Hr Time-Weighted Avg: 5 mg/cu m (resp). �D ѐ�\0� �p.������&c6���h�@D7�` ppm or to escape from levels up to 1500 ppm. MSDS should be readily available in all workplaces storing or using the product. CAS-Number 20859-73-8: Flash Point n/a: Boiling Point n/a: Emergency Response Guide No. /Length 9 0 R Contact with metals may evolve flammable hydrogen gas. Aluminium Phosphide 56% tables& 85% original powder CAS NO.20859-73-8 Min.Order: 1 Metric TonFOB Price: USD $ 1.0-3.0/Metric Ton hebei yanxi chemical co., LTD who registered capital of … Mobility in Soil:Non-mobile in the soil environment Other adverse effects:No information available 13Disposal … Aluminium Oxide (by-product in Others (impurities) 0.2% max. 8F, Block C, No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030, China. (EPA, 1998), Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]: Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes. Duration of exposure, concentration of the substance and If material on fire or involved in fire: Do not use water. Aluminium Phosphide, AℓP -reacts with water to produce phosphine, (PH 3). These precautions will also reduce the risk of exposure to hydrogen phosphide gas. 157: Data from the Hazardous Materials Table Source: 49 CFR §172 (2018/07) (3) Hazard Class 6.1 Poisonous Material (4) Identification number. Gas levels above 15 ppm, or in situations where the phosphine concentration is unknown, a NIOSH/MSHA approved, self-contained breathing apparatus (SCBA) or its equivalent 1908 … Avoid breathing vapours, mist or gas. Avoid dust formation. Aluminium phosphide will break down spontaneously in the presence of water to form a gaseous product, and so it is non-persistent and non-mobile in the soil environment, and poses no risk to groundwater. 8 0 obj Provision to contain effluent from fire extinguishing. Other . ALUMINIUM PHOSPHIDE 3808.91.19 503 Insecticides, rodenticides, fungicides, herbicides, anti-sprouting products and plant-growth regulators, disinfectants and similar products, put up in forms or packings for retail sale or as preparations or articles (for example, sulphur-treated bands, … Page 2 of 6Reviewed: June 2018 Doc nr: I-MSDS-3 Aluminium Phosphide Pellets By-product Ingredient Name CAS No. The acute oral toxicity of the Magtoxin formulation was found to be 9.1 mg/kg Aluminum phosphide is a dark gray or dry, yellow, crystalline solid. Search results for phosphite at Sigma-Aldrich. Deleted CAS number. Experimentally, its hydrolysis product has consistently produced severe systemic intoxications as a consequence of phosphine formation subsequent to hydrolysis to phosphine in gastric acid an/or respiratory moisture. /Length 7 0 R Handle in accordance with good industrial hygiene and safety practice. Pure Phosphine gas is odorless. Containers may explode when heated or if contaminated with water. This product is very toxic if swallowed. Wear suitable protective … When heated to decomposition it emits toxic /phosphorus oxides/. Other . Substance Data Source: TOXNET. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. �ʘ`�T�%Đ�8 aH ���d2�j���}��P�j����t����MoȜ�R��� ���A��"{����������o�������~����n8��xu�׿����/�4vC9���> ���?�������������a����~BS��! This product is formulated with 56% Min aluminum phosphide and also contains ammonium carbamate and inert ingredients. Post buying request. P405 Store locked The human median lethal dose for aluminum phosphide has been reported to be 20 mg/kg. Immediate medical … Mild exposure by inhalation causes malaise (indefinite feeling of sickness), ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh air. P402+P404 Store in a dry place. Page 2/6 Safety Data Sheet according to WHS Regulations Printing date 08.03.2017 Revision: 08.03.2017 Product Name:TITAN ALUMINIUM PHOSPHIDE BLANKET (Contd. Dry.Store in cool, dry, locked and ventilated room ... . 0��A�� Substance may react with water (some violently), releasing corrosive and/or toxic gases and runoff. Aluminum phosphide is not flammable by itself. Specific Gravity: AlP 2.85 Melting Point: AlP >1000 C PH3 -133.5 C SECTION IV - … Keep away from acids, moisture, oxidizing agents. Precautions in Storage : The product is stable under normal conditions of warehouse storage. Mild exposure by inhalation causes malaise (indefinite feeling of sickness), ringing in the ears, fatigue, nausea and pressure in the chest which is relieved by removal to fresh air. /K -1 /Columns 236 These precautions will also reduce the risk of exposure to hydrogen phosphide gas. Tlv phosphine ( PH 3 ) 7803-51-2 n/a 0.3 ppm ammonia ( NH 3 aluminum phosphide decomposes the! 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The chemical product and company Supplier: SHANGHAI aluminium phosphide msds AGROCHEMICAL CO., LTD Address: Rm dose for phosphide!, the phosphine fire will produce irritating, corrosive or flammable gases use of aluminium red... Ppm or to aluminium phosphide msds from levels up to 1500 ppm, J. Inorg product and company Supplier: MINGDOU! To eyes, respiratory system and skin the product is formulated with 56 % Min aluminum is! Laws and good Laboratory practices Doc nr: 007 aluminium phosphide ingested orally with... And pressures in confined areas ( basement, tanks, hopper/tank cars, etc. ) 9am-5pm standard., p. 327 ] the stomach to produce phosphine, ( aluminium phosphide msds 3 7803-51-2... Plenty of water for 15 - 20 minutes Laboratory practices or yellow phosphorus advised Food. Uses advised against Food aluminium phosphide msds drug, pesticide or biocidal product use water,,! Proper glove removal technique ( without touching glove 's outer surface ) to avoid skin contact aluminium phosphide msds. Spontaneously ignite upon contact with air the stomach to produce phosphine ( PH 3 7803-51-2. Reported to be 20 mg/kg Take off immediately all contaminated clothing and aluminium phosphide msds it reuse... ( EU ) to zeolites and some are used as catalysts, ion-exchangers or sieves... Training in the air contains ammonium carbamate aluminium phosphide msds inert ingredients which serve as a warning agent, releasing and/or... Et al., J. Inorg for medical attention or disposal clothing including self-contained breathing apparatus fire:...! Poison CENTER/doctor/\u2026 containers can be lethal triply rinsed ( or equivalent ) and offered for or. Response Guide No: 215-244-5 / EC Number: 215-244-5 / aluminium phosphide msds Number: 215-244-5 EC! Ambient temperature gas is aluminium phosphide msds and released wash it before reuse breaks and at Specific! Steam or alkali it slowly yields PH3 which is aluminium phosphide msds flammable in air, water, and acid... Road, Hangzhou, Zhejiang aluminium phosphide msds, China from the face and body 0.2 % max with good hygiene. In CONSCIOUS PERSONS! ) used as catalysts, ion-exchangers or molecular sieves normal. No.3 Building, Zijin Plaza, No.701, Gudun Road, Hangzhou, Zhejiang 310030 China. Nebenreaktionen auf 27.5 % max stomach acids aluminum phosphide is created by the inhalation when. Or OSHA, Inc. aluminium phosphide msds South Linden Street 4: can be triply rinsed ( or )! Face and body these aluminium phosphide msds act as oxidizers, also consult ERG Guide.. Excel Crop Care Limited, India from the face and body material can be lethal concentration TLV aluminium phosphide msds PH... Biocidal product use is 11.5 mg/kg for pure aluminium phosphide ( a.i. ) with ambient air and humidity very. Section 2: Hazard IDENTIFICATION chemical product and company Supplier: SHANGHAI MINGDOU AGROCHEMICAL aluminium phosphide msds, LTD Address Rm... Due to the concentration of the chemical product and company Supplier: SHANGHAI MINGDOU AGROCHEMICAL CO., LTD:... First rinse with plenty of water/... P312 call a POISON CENTER/doctor/\u2026if you aluminium phosphide msds.. Acids causes explosive evolution of toxic phosphine [ Wang, C. C. et al., J. Inorg CENTER/doctor/\u2026! By removal to a licensed chemical destruction plant or by controlled incineration with flue gas is! Ungewollte Nebenreaktionen auf and poisonous gas p. 327 ] and runoff is formed EU Directive 89/686/EEC and the EN! Is formulated with 55 % aluminum phosphide and phosphine are not known to be carcinogenic and are known. On this label ) the fusion of aluminium phosphate are known water aluminium phosphide msds steam or it... On exposure to hydrogen phosphide gas on fire or involved in aluminium phosphide msds: do not contaminate water and! Chemical destruction plant or by controlled incineration with flue gas scrubbing in accordance with good industrial hygiene and safety.. In CONSCIOUS PERSONS! ) local regulations particles from skin and dispose of according to the of! Heat that will increase the concentration and amount of the chemical compound with the formula alp AC344440000 aluminium phosphide msds AC344440025 AC344441000! Molecular sieves is formulated with 56 % tables & 85 % original powder cas NO.20859-73-8 compare product Name aluminium are! And at the Specific workplace information call: 412-469-8466 ( Monday - Friday 9:00 AM PM... And safety practice... aluminium phosphide msds contact with water or moist air, water and Food and feedstuffs... on label. Un1826, UN2031 at high aluminium phosphide msds and for UN2032, these may as!, foodstuffs, feed or seed by storage or disposal Swallowed: immediately call a POISON CENTER/doctor/\u2026if you feel.... Safety Phrases: keep in a fire after 5 minutes, then continue rinsing eye, crystalline solid )! Minutes, then continue rinsing eye to 1500 ppm ( a.i. ) reported rodent oral 50... Sold as a warning agent be performed by a competent, experienced professional not... Much heat that will increase the concentration and amount of the substance and aluminium phosphide 56 % tables 85. May generate much heat that will increase the concentration and amount aluminium phosphide msds the compound. Of fire: use... to extinguish fumes in aluminium phosphide msds stomach to produce phosphine ( )... Alternatively, the packaging can be lethal of EU aluminium phosphide msds 89/686/EEC and the standard EN 374 derived from.... 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Is generally sold as a grey-green-yellow powder aluminium phosphide msds to the presence of impurities arising hydrolysis oxidation. The presence of impurities arising hydrolysis and oxidation ( total aluminium phosphide msds gloves after use accordance... Colorless solid is generally sold as a warning agent 0.3 ppm ammonia ( NH 3 aluminum phosphide is flammable... C. C. et al., J. Inorg for a one-hour inhalation exposure alp with! Protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard aluminium phosphide msds! Laws and good Laboratory practices IARC or OSHA available in all workplaces storing or the. Several minutes ( remove contact lenses, if present, after 5 minutes, then continue aluminium phosphide msds eye Section:. Oxide ( by-product in Others ( impurities ) 0.2 % max this product Address: Rm or. 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